高分异花岗岩浆可能是华南花岗岩型铀矿床主要铀源——来自诸广山南体花岗岩锆石铀含量的证据     

伍皓  夏彧  周恳恳  张建军 《岩石学报》2020,36(2):589-600

锆石的U-Pb测年、Hf和O同位素及稀土、微量元素的研究与应用已获得诸多进展,但锆石中铀含量所蕴藏的地质意义却较少被关注。华南花岗岩型铀矿床的铀源一直存在争议,不同观点认为其分别来自早期已固结地质体、分异岩浆、地幔柱或热点以及U、Th、K富集圈。为尝试利用锆石中的铀含量来追索铀源,本文通过搜集诸广山南体花岗岩锆石U-Pb同位素测年文献,掌握了该花岗岩中14个岩体、37件样品、3种岩性,共467个锆石定年数据。通过数据分析发现印支期(253Ma、244Ma)和燕山期(139Ma、124Ma)具高分异特征的4件酸性岩脉(小岩体)样品中锆石的铀含量明显高于同期岩体。依据铀矿床中高分异酸性岩脉(小岩体)侵位期、基性岩脉侵位期、铀成矿早期(140~90Ma)三者的良好对应关系,结合这一锆石铀含量指示,初步认为华南花岗岩型铀矿床中铀可能主要来自高分异花岗岩浆;推测花岗岩型铀成矿可能属壳幔混合作用结果,即铀源来自地壳分异岩浆,成矿流体和矿化剂主要来自地幔,而成矿空间受断裂系统控制。岩体锆石铀含量或可在铀源丰度、矿床品位判别等方面发挥积极作用。  相似文献   

盾构隧道下穿管道施工引起的管-土相互作用研究     

可文海  管凌霄  刘东海  邓建林  李科  徐长节 《岩土力学》2020,41(1):221-228

采用Loganathan公式研究了盾构隧道下穿管道施工引起的地下管道处土体竖向位移，利用考虑土中剪力传递的Pasternak模型模拟管-土相互作用，运用修正Vlasov模型中的迭代流程计算出Pasternak模型的关键参数——弹性系数k与剪切系数gs。将计算结果与已有文献结果及工程监测数据进行对比，深入分析了迭代求解k、gs值的Pasternak模型与传统模型的计算差异，并进一步研究了土中剪力、管道与隧道的夹角、土体弹性模量及隧道半径的变化对管-土相互作用的影响。研究结果表明：迭代求解的k、gs值能提升Pasternak模型的精确度；土中剪力对管道竖向位移计算值的影响可达15.3%；随着管道与隧道夹角的减小，管道的竖向位移增大、弯矩减小；土体弹性模量与隧道半径的增大均会增加管道的竖向位移和弯矩。  相似文献   

羧乙基壳聚糖蒙脱石吸附养殖水体中Cu²⁺的应用     

李俭平  周忻宇  代婧炜  沈庆洲 《海洋科学》2020,44(2):120-130

为了寻求性能良好、环保吸附剂,用于去除养殖水体中重金属Cu~(2+),作者利用蒙脱石负载羧乙基壳聚糖制备成复合吸附剂,并利用IR、SEM、XRD等手段分析其表面性能,将其用于处理Cu~(2+)溶液,考察了环境因子对其吸附性能的影响,并从吸附动力学和吸附热力学角度分析吸附剂对Cu~(2+)的吸附机理,最后考察其再生利用效果。结果表明:羧乙基壳聚糖成功进入到蒙脱石层间;在羧乙基壳聚糖与蒙脱石质量比为1︰25、40℃恒温水浴搅拌60min、pH=6.0、最佳投加量为4.0g/L、处理浓度不超过30 mg/L Cu~(2+)溶液时,复合吸附剂对Cu~(2+)去除率可以达到96.23%,将其用于淡水养殖鱼塘水体中, Cu~(2+)去除后可达到《渔业水质标准》规定;吸附剂对Cu~(2+)吸附热力学实验结果表明,符合Langmuir模型,反应过程为自发、吸热反应;吸附动力学结果表明该吸附符合准二级动力学方程,反应属于化学吸附;再生实验中NaOH的再生效果优于HCl。  相似文献   

Effect of nano-MgO on mechanical performance of cement stabilized silty clay     

Kai Yao  Dongliang An  Na Li  Chen Zhang  Aizhao Zhou 《Marine Georesources & Geotechnology》2020,38(2):250-255

Abstract

A series of direct shear tests were performed on cement-admixed silty clay to investigate the effect of cement content and nano-magnesia (MgO) on its shear strength properties. For each normal stress, shear strength increased with cement content. However, an obvious increment in shear strength was achieved when the cement content was adjusted from 13% to 17%. Both cohesion and friction angle of cemented soil increased with cement content, and exponential function was adopted to correlate both the factors with cement content. For cement content of 10% investigated in this study, the optimum nano-MgO content was 10‰, wherein the cohesion could reach the peak value. The microstructure of the mixture revealed that the structure of the mixture was compacted for the optimum nano-MgO content. However, micro-cracks were formed when the amount of nano-MgO exceeded its optimum content.  相似文献   

Unified numerical study of shallow foundation on structured soft clay under unconsolidated and consolidated-undrained loadings     

Santosh Kumar Yadav  Guan-lin Ye  Usama Khalid 《Marine Georesources & Geotechnology》2020,38(4):400-416

Abstract

Based on a new elasto-plastic constitutive model, this paper presents a soil–water coupled numerical prediction of the bearing capacity for shallow foundation constructed on Ballina soft clay for unconsolidated undrained (UU) and consolidated undrained (CU) conditions. This elasto-plastic constitutive Shanghai model has an advantage of describing the mechanical behaviour of over-consolidated and structured soil under different loading and drainage conditions, by using one set of material parameter. In this paper, the Shanghai model used for both UU and CU conditions has the same initial parameters obtained from laboratory test results. The loading conditions and consolidation stages vary based on construction details. The predicted bearing pressure-settlement responses for UU and CU, approves the field observation. The phenomenon of gaining the bearing capacity due to consolidation is captured and explained by the use of soil–water coupled numerical analysis with a new elasto-plastic model. The stress strain behaviour, stress paths and the decay of the structure of elements at different depths presented in this study, reveal the mechanism for the difference between UU and CU conditions to understand the foundation behaviour. Effect of the initial degree of soil structure on the bearing capacity is also addressed. Overall, this approach provides the integrated solution for the shallow foundation design problems under short and long-term loadings.  相似文献   

Dynamic characteristics of marine soft clay under variable phase difference and initial static shear stress     

Wenqian Dong  Xiuqing Hu  Hongtao Fu 《Marine Georesources & Geotechnology》2020,38(7):770-785

Abstract

Under seismic loading, the soil layer is subjected to multidirectional cyclic shear stress with different amplitudes and frequencies because of the coupling of multiple shear waves and the soil element within a slope or behind a retaining wall is subjected to initial static shear stress before subjected to cyclic loading. Due to the complexity of seismic loading propagation, a phase difference exists between the initial static shear stress and cyclic shear stress. To investigate the influence of the phase difference and initial static shear stress on cyclic shear strain, cyclic modulus, and cyclic strength, a series of laboratory tests are performed on Wenzhou marine soft clay by multi-directional simple shear system, which can simulate the actual state better by controlling the horizontal cyclic stress in the x and y directions simultaneously. As the phase difference varies from 0° to 90°, the dynamic shear modulus increases and cyclic strain accumulation decreases with an increasing number of cycles. The shear strain increases with the initial shear stress.  相似文献   

Undrained monotonic shear behavior of marine soft clay after long-term cyclic loading     

Lin Guo  Hongxu Jin  Li Shi 《Marine Georesources & Geotechnology》2020,38(7):854-866

Abstract

In the coastal area, nearshore and offshore structures have been or will be built in marine soft clay deposits that have experienced long-term cyclic loads. Therefore, the mechanical behavior of marine clay after long-term cyclic loading needs to be investigated. In this research, a series of monotonic and cyclic triaxial tests were carried out to investigate the postcyclic mechanical behavior of the marine soft clay. The postcyclic water pore pressure, shear strength and secant stiffness are discussed by comparing the results with the standard monotonic test (without cyclic loading). It is very interesting that the postcyclic behavior of marine soft clay specimen is similar to the behavior of overconsolidated specimen, that is, the specimen shows apparent overconsolidation behavior after long-term cyclic loading. Then relationship between the overconsolidation ratio and the apparent overconsolidation ratio is established on the basis of the theory of equivalent overconsolidation. Finally, a validation formula is proposed which can predict the postcyclic undrained shear strength of marine soft clay.  相似文献   

海洋沉积物黏土矿物相对含量不同计算方法对比研究     

舒雨婷  刘志杰  余佳  孔敏  田先德  刘升发 《海洋通报》2019,(5):585-590

海洋沉积物黏土矿物相对含量计算存在多种计算方法,并不统一,限制了异源黏土矿物的整合和使用。文章选取了两种较为常见的计算方法,即Biscaye和国标中规定的计算方法,分别对东印度洋109个表层样品黏土矿物的相对百分含量进行计算,分析对比了两种方法计算结果之间的差异。结果显示,两种计算方法结果存在显著正相关,都能显示黏土矿物分布的变化趋势,4种黏土矿物相关系数由高到底分别为:蒙皂石0.986、伊利石0.974、绿泥石0.924、高岭石0.923。相对于Biscaye计算方法,国标计算方法会增加伊利石和高岭石的相对百分含量而降低蒙皂石和绿泥石的相对百分含量。两种计算方法黏土矿物的含量相关性较好,可以建立起相互数学转换关系式。但在不同的海区,由于矿物成因、结晶程度以及混层矿物的出现可能会使衍射峰形态发生改变,从而相关性系数和转换关系也会相应发生改变。  相似文献   

A finite element approach for predicting the full resistance profile of a spudcan deeply penetrating in dense sand overlying clay     

《Applied Ocean Research》2019

This paper presents a finite element approach to calculate the full resistance profile of a spudcan deeply penetrating in dense sand overlying clay, in which a potential for an installing spudcan to experience a sudden uncontrolled punch-through failure exists. A modified Mohr-Coulomb model characterized by incorporating a four-phase variation of the mobilized strength and dilation parameters with an equivalent accumulated plastic strain is developed and tested for the overlying dense silica sand. An extended Tresca model is used for the strain softening of the underlying clay. A series of large deformation finite-element (LDFE) analyses are carried out, varying the strength and dilation parameters as well as the spudcan geometries. A fairly good performance of the present approach is verified by validating against groups of centrifuge tests data, allowing the numerical study to be extended parametrically. The four-phase variation of the mobilized strength and dilation parameters involved in the progressive failure of the upper dense sand is parametrically studied and extended to cover the range of sand relative densities that are of practical interest. Additionally, comparisons with the typical existing LDFE analyses using both simple and sophisticated constitutive models are carried out. It shows that the present approach performs fairly well to calculate the full resistance profile of a spudcan deeply penetration in both thin and thick dense sand overlying clay, especially the peak and post-peak resistance, within around 5% of the corresponding centrifuge tests results.  相似文献   

Bound and mobile soil water isotope ratios are affected by soil texture and mineralogy,whereas extraction method influences their measurement     

Rachel E. Adams  Ayumi Hyodo  Toby SantaMaria  Cynthia L. Wright  Thomas W. Boutton  Jason B. West 《水文研究》2020,34(4):991-1003

Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ²H and δ¹⁸O of soil water isotope ratios.  相似文献